After 118 years, the isolation of two common radical anion reductants as simple, stable solids.
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Academic Article
individual record
abstract
Two common radical anion reductants, potassium benzophenone ketyl (K(Ph(2)CO)) and potassium naphthalenide (K(2)(C(10)H(8))(2)(THF)), have been isolated and characterized for the first time in solvent-free form or with low solvent content, allowing their use as pure solid reactants in preparative redox chemistry in accurate stoichiometric amounts.
authors
publication outlet
Chem Commun (Camb)
author list (cited authors)
Scott, T. A., Ooro, B. A., Collins, D. J., Shatruk, M., Yakovenko, A., Dunbar, K. R., & Zhou, H.
publication date
2009
publisher
Royal Society of Chemistry (RSC)
Publisher
keywords
- 0306 Physical Chemistry (incl. Structural)
altmetric score
3.0
citation count
62
PubMed ID
19082000
identifier
37720SE
Digital Object Identifier (DOI)
start page
65
end page
67
volume
0
issue
1