Adenine-containing block copolymers via ring-opening metathesis polymerization: Synthesis and self-assembly into rod morphologies | Academic Article individual record
abstract

The first synthesis of adenine-containing polymers and block copolymers using the ring-opening metathesis polymerization of non-covalently protected monomers are shown. Studies of the copolymer 9 reveal an unexpected cylindrical morphology, which can be interpreted as arising from the hydrogen-bonding self-complementarity of the adenine units in the micellar core. Thus, further studies are currently conducted to fully characterize this morphogenesis mechanism as well as to study the effect of hydrogen-bonding guests on the polymer morphologies.

authors
author list (cited authors)
Bazzi, H. S., & Sleiman, H. F.
publication date
2002
published in
altmetric score

3.0

citation count

66